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0 μm and smaller. Hydration of C2S occurs in a similar manner as for C3S, however at significantly lower rates and with significantly less heat evolved. 6. C3A out of all the clinker minerals has the highest reactivity. 7) Primary unstable calcium aluminate hydrates have the form of hexagonal plate crystals. These form a fluffy water-permeable shell on the surface of C3A grains. 8) Cubic-shaped C3AH6 crystals also take part in forming fluffy water-permeable shells on the surface of C3A grains. Fluffy shells formed practically do not prevent or slow down the process of C3A hydration, which ends by a quick ‘false’ setting and hardening of a hydrated C3A paste.
26 Cementitious Materials for Nuclear Waste Immobilization IAEA (1995) The Principles of Radioactive Waste Management, Safety Series No. 111-F. IAEA, Vienna. IAEA (1998) Management of Radioactive Waste from 99Mo Production, IAEA-TECDOC-1051. IAEA, Vienna. IAEA (1999a) Minimization of Waste from Uranium Purification, Enrichment and Fuel Fabrication, IAEA-TECDOC-1115. IAEA, Vienna. IAEA (1999b) Review of the Factors Affecting the Selection and Implementation of Waste Management Technologies, IAEA-TECDOC-1096.
2011) Glassy wasteforms for nuclear waste immobilisation. Metallurgical and Materials Transactions A, 42 (4), 837–851. I. E. (2014) An Introduction to Nuclear Waste Immobilization, 2nd edn, Elsevier, Amsterdam. 1 Cements Cements are powdery mineral binders, which after mixing with water or water solutions of some salts form a yielding mass able to go hard over time and convert into a stone-like state as a result of physico-chemical processes. The development history of types, production and use of cementitious materials is closely associated with the history of civilization.