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66 The adduct (303; R = SiMe3) of tetrafluorobenzyne to N-trimethylsilylpyrrole was hydrolysed to compound (303; R = H), which added benzonitrile phenylimine, PhC&-NPh, to yield the condensed pyrazoline (304). Thermal fragmentation of the latter gave 1,3-diphenylpyrazole and tetrafluoroisoindole (305). -Formation. Phenacyltriphenylarsonium bromide, P h 3 k H 2 C O P h Br-, reacts with aniline to give 2-phenylindole. ”~ Treatment Ac (306) 165 16’ 16’ 169 (307) (308) T. Momose, T. Tanaka, and T.

Grinev, A. K . Chizhov, and T. F. Vlasova, Khim. geterotsikl. Soedinenii, 1977, 766. W. Rettig and J. Wirz, Helv. Chim. Acta, 1978,61, 444. R. D. Hamilton and E. Campaigne, Chem. Heterocyclic Compounds, 1977, 30, 271 (Chem. , 1977,87, 201 366). V. P. Litvinov and Ya. L. Goldfarb, Adu. , 1976, 19, 123. P. Bouchet, C. Coquelet, and J. Elguero, Bull. chim. France, 1977,171. M. I. Knyazhanskii, P. V. A. Osipov, Khim. geterotsikl. Soedinenii, 1977, 1455. r. r. 20'Compound (373), obtained from the lQ8 lW 200 '01 '02 ' 0 3 '05 H.

P. Hiremath, S. S. Kaddargi, and M. G. Purohit, Indian J. , 1977, 15B,1103. A. N. Grinev, A. K . Chizhov, and T. F. Vlasova, Khim. geterotsikl. Soedinenii, 1977, 766. W. Rettig and J. Wirz, Helv. Chim. Acta, 1978,61, 444. R. D. Hamilton and E. Campaigne, Chem. Heterocyclic Compounds, 1977, 30, 271 (Chem. , 1977,87, 201 366). V. P. Litvinov and Ya. L. Goldfarb, Adu. , 1976, 19, 123. P. Bouchet, C. Coquelet, and J. Elguero, Bull. chim. France, 1977,171. M. I. Knyazhanskii, P. V. A. Osipov, Khim. geterotsikl.

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