By F. Gordon (ed.), A. Stone (ed.), Robert West (ed.)
This greatly acclaimed serial includes authoritative stories that handle all points of organometallic chemistry, a box which has improved vastly because the e-book of quantity 1 in 1964. just about all branchesof chemistry now interface with organometallic chemistry-the research of compounds containing carbon-metal bonds. Organometallic compounds diversity from species that are so reactive that they just have a temporary life at ambient temperatures to species that are thermally very solid. Organometallics are used generally within the synthesis of necessary compounds on either huge and small scales. business tactics regarding plastics, polymers, digital fabrics, and prescription drugs all depend upon developments in organometallic chemistry. Key good points* In easy study, organometallics have contributed inter alia to:* steel cluster chemistry* floor chemistry* The stabilization of hugely reactive species via steel coordination* Chiral synthesis* The formula of a number of bonds among carbon and the opposite parts and among the weather themselves
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Extra resources for Advances in Organometallic Chemistry, Vol. 37
NMR Characteristics of Allenyl Clusters . . , . . . . A. Mononuclear Allenyl and Propargyl Complexes . . . . B. Binuclear Allenyl Complexes . . . . . . . . C. Trinuclear Allenyl Clusters . . . . . . . . Ligand Dynamics: Solution NMR Studies , , . . . . . Reactivity. . , , . , . . . . . , . . . . A. Reactivity of o-Bound Propargyl and Allenyl Ligands . . B. Reactions of Allenyl Ligands Bound to Two Metal Centers . C. Reactions of Cluster-Bound Allenyl Groups .
CARTY Guelph-Waterloo Centre for Graduate Work in Chemistry Waterloo Campus, Department of Chemistry University of Waterloo, Waterloo Ontario, Canada N2L 3 6 1 ENRICO SAPPA Dipartimento di Chimica Inorganice, Chimica Fisica e Chimica dei Materiali Universita di Torino, Via Pietro Giuria 7, 1-10125 Torino lfaly .. .......... ... . Preparation of Mononuclear Propargyl, Allenyl, and Allenylidene Complexes . . . . . . . . . . . . , . Propargyl Complexes as Source ofAllenyl Groups . .
Jpn. Chem. Soc. 1993, W A h s t r a c t I ) . 342. ; Masumoto. ; Kyushin, S . ; Matsumoto, H. Appl. Phys. Lett. 1992,61,2446; Kanemitsu, Y . : Suzuki. ; Higuchi. ; Kyushin, S . ; Matsumoto, H. Jpn. J . Appl. Phys. 1993,32, 408. (41) Masamune, S . ; Hanzawa, Y . ; Murakami. S . ; Blount. J. F. J . A m . Chem. Soc. 1982, 146, 1150. (42) Masamune, S . ; Williams. D. J . J . Am. Chem. Soc. 1982, 104, 6136. (43) Karl. R . R . : Gallaher, K. ; Wang, Y. C . ; Bauer, S . H. unpublished results cited in J .